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[1]董晓囡,张 建*,郭奇勋,等.Kr离子辐照磷灰石陶瓷材料Ca10(PO4)6FxCl2-x(x=0,0.5,1.0,1.5和2.0)导致的非晶相变[J].厦门大学学报(自然科学版),2018,57(01):38-43.[doi:10.6043/j.issn.0438-0479.201703034]
 DONG Xiaonan,ZHANG Jian*,GUO Qixun,et al.Amorphization of Ca10(PO4)6FxCl2-x(x=0,0.5,1.0,1.5,2.0)Apatite Ceramics Caused by Kr Ion Irradiation[J].Journal of Xiamen University(Natural Science),2018,57(01):38-43.[doi:10.6043/j.issn.0438-0479.201703034]
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Kr离子辐照磷灰石陶瓷材料Ca10(PO4)6FxCl2-x(x=0,0.5,1.0,1.5和2.0)导致的非晶相变(PDF/HTML)
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《厦门大学学报(自然科学版)》[ISSN:0438-0479/CN:35-1070/N]

卷:
57卷
期数:
2018年01期
页码:
38-43
栏目:
研究论文
出版日期:
2018-01-26

文章信息/Info

Title:
Amorphization of Ca10(PO4)6FxCl2-x(x=0,0.5,1.0,1.5,2.0)Apatite Ceramics Caused by Kr Ion Irradiation
文章编号:
0438-0479(2018)01-0038-06
作者:
董晓囡张 建*郭奇勋焦绪丽林绍辰李 宁
厦门大学能源学院,福建 厦门 361102
Author(s):
DONG XiaonanZHANG Jian*GUO QixunJIAO XuliLIN ShaochenLI Ning
College of Energy,Xiamen University,Xiamen 361102,China
关键词:
关键词:六方结构磷灰石 离子辐照 非晶转变
Keywords:
hexagonal apatite ion irradiation amorphous transition
分类号:
TL 11
DOI:
10.6043/j.issn.0438-0479.201703034
文献标志码:
A
摘要:
采用传统的陶瓷烧结工艺制备了六方结构的多晶磷灰石陶瓷材料Ca10(PO4)6FxCl2-x(x=0,0.5,1.0,1.5和2.0),并通过常规X射线衍射(X-ray diffraction,XRD)确认其为单一相.然后,用800 keV Kr2+在室温下辐照各磷灰石样品,辐照后的样品利用掠入射X射线衍射(grazing incidence X-ray diffraction,GIXRD)对其表面辐照损伤层结构进行表征.结果表明,当用Kr2+对该系列磷灰石样品进行辐照时,所有样品都会发生从晶体到非晶体结构的转变,但同种辐照剂量下,该系列磷灰石样品中含F比例越高,Kr2+辐照导致的非晶含量就越小,其抗辐照非晶转变能力越强.
Abstract:
A series of hexagonal polycrystalline apatite ceramics Ca10(PO4)6FxCl2-x(x=0,0.5,1.0,1.5,2.0)were synthesized by a conventional ceramic process, and the single-phase was confirmed by normal X-ray diffraction(XRD).Then,the apatite samples were irradiated with 800 keV Kr2+ at room temperature.The irradiated samples were characterized using grazing incidence X-ray diffraction(GIXRD).Crystalline-to-amorphous transition was observed in these apatite samples under 800 keV Kr2+ ion irradiation.However,it was found that the apatite sample with higher F proportion had smaller amorphous fraction with the same irradiation dose based on a series of irradiation experiments.Namely,the apatite with higher F proportion would have stronger ability to resist amorphization of Ca10(PO4)6FxCl2-x.

参考文献/References:

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[4] CHAIRAT C,OELKERS E H,SCHOTT J,et al.An experimental study of the dissolution rates of Nd-britholite,an apatite-structured actinide-bearing waste storage host analogue[J].Journal of Nuclear Materials,2006,354(1/2/3):14-27.
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[6] GAILLARD A,CHEVARIER A,MILLARD P,et al.Thermal diffusion of molybdenum in apatite[J].Nuclear Instruments and Methods in Physics Research Section B:Beam Interactions with Materials and Atoms,2000,161(3):646-650.
[7] LIAN J,ZHANG J M,WANG L M,et al.Ion irradiation-induced amorphization in vanadate-phosphate apatites[J].Microscopy Society of America,2010,16(2):1634-1635.
[8] SOULET S,CHAUMONT J,KRUPA J C,et al.Determination of the defect creation mechanism in fluoroapatite[J].Journal of Nuclear Materials,2001,289(1/2):194-198.
[9] SHUSTER D L,FARLEY K A.The influence of artificial radiation damage and thermal annealing on helium diffusion kinetics in apatite[J].Geochimica Et Cosmochimica Acta,2009,73(1):183-196.
[10] ZIEGLER J F,ZIEGLER M D,BIERSACK J P.SRIM:the stopping and range of ions in matter(2010)[J].Nuclear Instruments and Methods in Physics Research Section B:Beam Interactions with Materials and Atoms,2010,268(11/12):1818-1823.
[11] BI Z,UBERUAGE B P,VERNON L J,et al.Radiation damage in heteroepitaxial BaTiO3thin films on SrTiO3 under Ne ion irradiation[J].Journal of Applied Physics,2013,113(2):023513-023518.
[12] 黄志良,刘羽,王大伟,等.通道离子替换磷灰石固溶体比较晶体化学XRD研究[J].无机化学学报,2002,18(10):976-980.
[13] JAMES A V,ZHEN H C.Light ion irradiation-induced phase transformation in the monoclinic polymorph of zirconia[J].Journal of Nuclear Materials,2008,381(3):259-266.
[14] TSUJI K,SATO S,HIROKAWA K.Depth profiling using the glancing incidence and glancing takeoff X ray fluorescende method[J].Review of Scientific Instruments,1995,66(10):4847-4852.
[15] 黄继武,李周.多晶材料X射线衍射[M].北京:冶金工业出版社,2013:120-129.
[16] TANG M,LU P,SICKAFUS K E,et al.Ion-irradiation-induced phase transformation in rare earth sesquioxides(Dy2O3,Er2O3,Lu2O3)[J].Journal of Applied Physics,2006,99(6):063514.
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备注/Memo

备注/Memo:
收稿日期:2017-03-21 录用日期:2017-05-03
基金项目:国家自然科学基金(11205128,11227804)
*通信作者:zhangjian@xmu.edu.cn
更新日期/Last Update: 1900-01-01