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[1]郑潇潇,谢 婷,肖 玥,等.原位还原制备Au-P/SiO2催化剂及其催化性能[J].厦门大学学报(自然科学版),2017,56(01):42-47.[doi:10.6043/j.issn.0438-0479.201601039]
　ZHENG Xiaoxiao,XIE Ting,XIAO Yue,et al.Au-P/SiO2 Prepared with In situ Reduction and Its Catalytic Performance[J].Journal of Xiamen University(Natural Science),2017,56(01):42-47.[doi:10.6043/j.issn.0438-0479.201601039]
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原位还原制备Au-P/SiO2催化剂及其催化性能(PDF)
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《厦门大学学报（自然科学版）》[ISSN:0438-0479/CN:35-1070/N]

卷:
56卷
期数:
2017年01期
页码:
42-47
栏目:
研究论文
出版日期:
2017-01-23

文章信息/Info

Title:
Au-P/SiO2 Prepared with In situ Reduction and Its Catalytic Performance
文章编号:
0438-0479(2017)01-0042-06
作者:
郑潇潇; 谢 婷; 肖 玥; 张鸿斌; 张来英; 李海燕*
厦门大学 化学化工学院,固体表面物理化学国家重点实验室,醇醚酯化工清洁生产国家工程实验室,福建 厦门 361005
Author(s):
ZHENG Xiaoxiao; XIE Ting; XIAO Yue; ZHANG Hongbin; ZHANG Laiying; LI Haiyan*
State Key Laboratory of Physical Chemistry of Solid Surfaces,National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China
关键词:
次亚磷酸钠;  Au-P复合物;  磷酸金;  甲酸分解
Keywords:
sodium phosphinate;  Au-P compound;  gold phosphate;  formic acid decomposition
分类号:
O 641
DOI:
10.6043/j.issn.0438-0479.201601039
文献标志码:
A
摘要:
甲酸分解制氢是解决能源问题的有效途径,与Pd催化剂相比,Au催化剂不易失活,具有较好的稳定性.使用次亚磷酸钠原位还原制备了Au-P/SiO2催化剂,并利用X射线衍射、透射电子显微镜和X射线光电子能谱等表征手段探讨其结构,并以甲酸分解为目标反应研究其催化性能.结果表明,该方法制备的催化剂中Au粒子(粒径3 nm左右)均匀分散在SiO2表面,且P掺杂进入Au的晶格形成Au-P复合物,改变了Au的电子结构.同时反应过程中产生的PⅢ被Au3+氧化生成磷酸金,提供酸性中心,使Au-P/SiO2催化剂表现出较Au/SiO2催化剂更加优越的催化性能.在363 K,4 mol/L的甲酸溶液中,Au-P/SiO2催化剂催化甲酸分解的转化率可达51%,是未掺杂的Au/SiO2催化剂的4倍.
Abstract:
Formic acid decomposition is an effective way to solve energy problem.Compared with Pd catalysts,Au catalysts have better anti-inactivation ability.In this article,Au-P/SiO2 catalysts were prepared with in situ reduction using NaH2PO2.The catalysts were characterized by X-ray diffraction,transmission electron microscope,X-ray photoelectron spectroscopy,and catalytic performances of the catalysts were tested through catalytic decomposition of formic acid.The results of the catalyst characterization demonstrated that with this method, the Au particles(3 nm)highly dispersed on the surface of SiO2,and some P entered into the crystal lattice of Au,which contributed the formation of Au-P compound and changed the electrical property of Au.Meanwhile,in the process of reaction,PⅢ appeared,and it was oxidized into PⅤ by Auδ+ to form gold phosphate with acid-base properties.For the reasons above,Au-P/SiO2 is more active than Au/SiO2.In 363 K,4 mol/L formic acid solution,the conversion rate of formic acid reached 51% over Au-P/SiO2,which is 4 times of Au/SiO2.

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备注/Memo

备注/Memo:
收稿日期:2016-01-20 录用日期:2016-04-22
基金项目:国家重点基础研究发展计划(973计划)项目(2011CBA00500); 福建省自然科学基金(E0510001)
*通信作者:hyli@xmu.edu.cn
更新日期/Last Update: 1900-01-01