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[1]王 爽,袁丛辉,朱继红,等.异形聚合物纳米球的制备及其作为催化剂载体和光子晶体基元的性能[J].厦门大学学报(自然科学版),2017,56(01):33-41.[doi:10.6043/j.issn.0438-0479.201603042]
　WANG Shuang,YUAN Conghui,ZHU Jihong,et al.Preparation and Property of Asymmetric Polymer Nanospheres as Catalyst Supports and Photonic Crystal Building Blocks[J].Journal of Xiamen University(Natural Science),2017,56(01):33-41.[doi:10.6043/j.issn.0438-0479.201603042]
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异形聚合物纳米球的制备及其作为催化剂载体和光子晶体基元的性能(PDF/HTML)
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《厦门大学学报（自然科学版）》[ISSN:0438-0479/CN:35-1070/N]

卷:
56卷
期数:
2017年01期
页码:
33-41
栏目:
研究论文
出版日期:
2017-01-23

文章信息/Info

Title:
Preparation and Property of Asymmetric Polymer Nanospheres as Catalyst Supports and Photonic Crystal Building Blocks
文章编号:
0438-0479(2017)01-0033-09
作者:
王 爽; 袁丛辉; 朱继红; 陈国荣; 许一婷; 曾碧榕; 罗伟昂; 戴李宗*
厦门大学 材料学院,福建省防火阻燃材料重点实验室,福建 厦门 361005
Author(s):
WANG Shuang; YUAN Conghui; ZHU Jihong; CHEN Guorong;  XU Yiting; ZENG Birong; LUO Weiang; DAI Lizong*
Fujian Province Key Laboratory of Fire Retardant Materials,College of Materials,Xiamen University,Xiamen 361005,China
关键词:
异形聚合物纳米球;  催化剂载体;  光子晶体
Keywords:
asymmetric polymer nanosphere;  catalyst support;  photonic crystal
分类号:
O 632
DOI:
10.6043/j.issn.0438-0479.201603042
文献标志码:
A
摘要:
采用无皂乳液聚合,以过硫酸钾(K2S2O8)为引发剂、苯乙烯(St)为疏水单体、甲基丙烯酸缩水甘油酯(GMA)为亲水单体与亲/疏水性各异的交联剂进行反应,制备交联异形聚苯乙烯-聚甲基丙烯酸缩水甘油酯(PSt-PGMA)聚合物纳米球.利用扫描电镜、动态光散射、红外光谱、热重分析等手段对材料进行表征,探讨异形聚合物纳米球形貌的调控方法和形成机理.结果表明,交联剂的亲/疏水性是控制聚合物纳米球形态的关键因素.该聚合物纳米球可作为Au纳米粒子载体用于催化对硝基苯酚的还原反应.同时,通过垂直沉积法诱导尺寸各异的交联异形PSt-PGMA聚合物纳米球自组装,可获得颜色从红到紫连续变化的光子晶体材料.
Abstract:
Poly(styrene-co-divinylbenzene-co-polyglycidyl methacrylate)(PSt-PDVB-PGMA)polymer nanospheres with tunable morphologies have been prepared through emulsion polymerization using potassium persulfate(K2S2O8)as an initiator,styrene(St)and glycidyl methacrylate(GMA)as monomers in the presence of different crosslinking agents.Scanning electron microscope(SEM),dynamic light scattering(DLS),thermogravimetric analysis(TGA)and Fourier transform-infrared spectroscopy(FT-IR)were used to characterize the morphology,size and composition of the polymer nanospheres.The mechanism for the formation of asymmetric polymer nanospheres and control over morphology were discussed in detail.It was found that the hydrophilicity of the crosslinking agent significantly affected the final morphology of the polymer nanospheres.The PSt-PDVB-PGMA polymer nano-spheres can be used as supports for Au nanocatalyst to catalyze the reduction of nitrophenol and self-assembly building blocks to form photonic crystals.

参考文献/References:

[1] FUNG E Y K,MUANGNAPOH K,WATSON C M L.Anisotropic photonic crystal building blocks:colloids tuned from mushroom-caps to dimmers[J].Journal of Materials Chemistry,2012,22:10507-10513.
[2] VELIKOV K P,DILEN T V,POLMAN A.Photonic crystals of shape-anisotropic colloidal particles[J].Applied Physics Letters,2002,81(5):838-840.
[3] GE J P,YIN Y D.Responsive photonic crystals[J].Angew Chem Int Ed,2011,50:1492-1522.
[4] BINKS B P,FLETCHER P D I.Particles adsorbed at the oil-water interface:a theoretical comparison between spheres of uniform wettability and "Janus" particles[J].Langmuir,2001,17(16):4708-4710.
[5] GLOTZER S C.Some assembly required[J].Science,2004,306(15):419-420.
[6] QI D M,BAO Y Z,HUANG Z M,et al.Anchoring of polyacrylate onto silica and formation of polyacrylate/silica nanocomposite particles via in situ emulsion polymerization[J].Colloid and Polymer Science,2008,286:233-241.
[7] ZHANG Z L,HORSCH M A,LAMM M H,et al.Tethered nano building blocks:toward a conceptual framework for nanoparticle self-assembly[J].Nano Letters,2003,3(10):1341-1346.
[8] KAEWSANEHA C,BITAR A,TANBORIBOONRAT P,et al.Fluorescent-magnetic Janus particles prepared via seed emulsion polymerization[J].Journal of Colloid and Interface Science,2014,424:98-103.
[9] CHADUC I,GIROD M,ANTOINE R,et al.Batch emulsion polymerization mediated by poly(methacrylic acid)macro RAFT agents:one-pot synthesis of self-stabilized particles[J].Macromolecules,2012,45:5881-5893.
[10] QIANG W L,WANG Y L,HE P,et al.Synthesis of asymmetric inorganic/polymer nanocomposite particles via localized substrate surface modification and miniemulsion polymerization[J].Langmuir,2008,24(3):606-608.
[11] NAGAO D,HASHIMOTO M,HAYASAKA K,et al.Synthesis of anisotropic polymer particles with soap-free emulsion polymerization in the presence of a reactive silane coupling agent[J].Macromol Rapid Commun,2008,29(17):1484-1488.
[12] SUN Y J,LIANG F X,QU X Z,et al.Robust reactive Janus composite particles of snowman shape[J].Macromolecules,2015,48(8):2715-2722.
[13] FOWLER C I,MUCHEMU C M,MILLER R E,et al.Emulsion polymerization of styrene and methyl metha-crylate using cationic switchable surfactants[J].Macromolecules,2011,44(8):2501-2509.
[14] FUJIBAYASHI T,OKUBO M.Preparation and thermodynamic stability of micron-sized,monodisperse composite polymer particles of disc-like shapes by seeded dispersion polymerization[J].Langmuir,2007,23(15):7958-7962.
[15] OKUBO M,MINAMI H.Production of micro-sized monodispersed anomalous polymer particles having red blood corpuscle shape[J].Macromol Symp,2000,150:201-210.
[16] WANG J X,WEN Y Q,GE H L,et al.Simple fabrication of full color colloidal crystal films with tough mechanical strength[J].Macromolecular Chemistry and Physics,2006,207(6):596-604.
[17] HUANG Y,WANG J X,ZHOU J M,et al.Controllable synthesis of latex particles with multicavity structures[J].Macromolecules,2011,44(8):2404-2409.
[18] SHI S,KURODA S I,KUBOTA H.Anomalous particles formed in two-stage soap-free emulsion polymerization of styrene on poly(2-acetoxyethyl methacrylate)[J].Colloid and Polymer Science,2003,281:331-336.
[19] GE X P,GE X W,WANG M Z,et al.A novel approach for preparation of "cage-like" multihollow polymer microspheres through sulfonated polystyrene particles[J].Colloid and Polymer Science,2012,290:1749-1757.
[20] LU Y,YIN Y,XIA Y N.Three-dimensional photonic crystals with non-spherical colloids as building blocks[J].Adv Mater,2001,13(6):415-420.
[21] YIN S N,YANG S Y,WANG C F,et al.Magnetic-directed assembly from Janus building blocks to multiplex molecular-analogue photonic crystal structures[J].J Am Chem Soc,2016,138(2):566-573.
[22] LI W P,SHANMUGAM V,Huang C C,et al.Eccentric inorganic-polymeric nanoparticles formation by thermal induced cross-linked esterification and conversion of eccentricity to raspberry-like Janus[J].Chem Commun,2013,49:1609-1611.
[23] CHEN T,ZHANG C L,LIU J Q,et al.Large scale synthesis of Janus submicrometer sized colloids by seeded emulsion polymerization[J].Macromolecules,2010,43(11):5114-5120.
[24] WANG R K,LIU H R,WANG F W.Facile preparation of raspberry-like superhydrophobic polystyrene particles via seeded dispersion polymerization[J].Langmuir,2013,29(36):11440-11448.
[25] GE X W,WANG M Z,WANG H,et al.Novel walnut-like multihollow polymer particles:synthesis and morphology control[J].Langmuir,2010,26(3):1635-1641.
[26] 王芳平,张珺瑛,袁婷,等.PBMA-GMA-SiO2纳米复合材料的制备及表征[J].西北师范大学学报(自然科学版),2013,49(5):70-73.
[27] KIM S,JANG J.The measurement of degree of conversion for BIS-GMA/silica composites by FT-IR spectroscopy[J].Polymer Testing,1996,15:559-571.
[28] LU C Q,YANG L,WANG J,et al.One-pot synthesis of octahedral Cu2O nanocages via a catalytic solution route[J].Advanced Materials,2005,17(21):2562-2567.
[29] 陈金妹,谈萍,王建永.气体吸附法表征多孔材料的比表面积及孔结构[J].粉末冶金工业,2011,21(2):45-49.
[30] XU S P,HARLVICKSON S,ZHAO X J.Increasing surface area of silica nanoparticles with a rough surface[J].ACS Applied Materials & Interfaces,2011,3(6):1865-1872.
[31] 于冰,王少鹏,丛海林,等.光子晶体的制备与应用进展[J].化学通报,2012,75(3):216-223.
[32] SU B,WU Y C,JIANG L.The art of aligning one-dimensional(1D)nanostructures[J].Chem Soc Rev,2012,41(23):7832-7856.

备注/Memo

备注/Memo:
收稿日期:2016-03-28 录用日期:2016-05-06
基金项目:国家科技支撑计划项目(2014BAF08B03); 福建省重大科技平台建设基金(2014H2006); 厦门市科技计划项目(3502Z20150047); 中央高校基本科研业务费专项(20720140542,20720140516)
更新日期/Last Update: 1900-01-01