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[1]邓林龙*,谢素原,黄荣彬,等.钙钛矿太阳能电池材料和器件的研究进展(综述)[J].厦门大学学报(自然科学版),2015,54(05):619-629.[doi:10.6043/j.issn.0438-0479.2015.05.005]
 DENG Lin-long*,XIE Su-yuan,HUANG Rong-bin,et al.Research Progress in Perovskite Solar Cell Materials and Devices[J].Journal of Xiamen University(Natural Science),2015,54(05):619-629.[doi:10.6043/j.issn.0438-0479.2015.05.005]
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钙钛矿太阳能电池材料和器件的研究进展(综述)(PDF)
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《厦门大学学报(自然科学版)》[ISSN:0438-0479/CN:35-1070/N]

卷:
54卷
期数:
2015年05期
页码:
619-629
栏目:
电池材料
出版日期:
2015-09-28

文章信息/Info

Title:
Research Progress in Perovskite Solar Cell Materials and Devices
文章编号:
0438-0479(2015)05-0619-11
作者:
邓林龙1*谢素原2黄荣彬2郑兰荪2
1.厦门大学萨本栋微米纳米科学技术研究院,2.厦门大学 化学化工学院,固体表面物理化学国家重点实验室,福建 厦门 361005
Author(s):
DENG Lin-long1*XIE Su-yuan2HUANG Rong-bin2ZHENG Lan-sun2
1.Pen-Tung Sah Institute of Micro-Nano Science and Technology,Xiamen University,2.State Key Laboratory of Physical Chemistry of Solid Surfaces,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China
关键词:
钙钛矿 太阳能电池 器件结构
Keywords:
perovskite solar cells device structure
分类号:
TM 914
DOI:
10.6043/j.issn.0438-0479.2015.05.005
文献标志码:
A
摘要:
基于金属有机卤化物吸光材料的钙钛矿太阳能电池是一种新型太阳能电池,近年来钙钛矿太阳能电池发展迅速,其光电转换效率从2009年的3.8%快速增加到2014年的20.1%,引起人们的广泛关注.本文系统总结了钙钛矿太阳能电池在材料和器件方面的研究进展,分析了钙钛矿太阳能电池发展中存在的主要问题,尤其是对稳定性问题进行了深入探讨,并提出了提高电池稳定性的途径和方法,预示了今后钙钛矿太阳能电池的发展方向.
Abstract:
Perovskite solar cell based on organometal halide ligh-absorbing material is a new type of solar cell,with its power conversion efficiency increasing from 3.8% in 2009 up to 20.1% in 2014,and has attracted much attention with its rapid development in recent years.In this review,the research progress in photovoltaic materials and devices of perovskite solar cells is summarized,the main problems existing in the development of perovskite solar cells are analyzed,especially the stability problem,and approaches to improve the stability of devices and future development of perovskite solar cells are discussed.

参考文献/References:

[1] Kojima A,Teshima K,Shirai Y,et al.Organometal halide perovskites as visible-light sensitizers for photovoltaic cells[J].J Am Chem Soc,2009,131(17):6050-6051.
[2] Zhou H,Chen Q,Li G,et al.Interface engineering of highly efficient perovskite solar cells[J].Science,2014,345(6196):542-546.
[3] Green M A,Emery K,Hishikawa Y,et al.Solar cell efficiency tables(version 45)[J].Prog Photovolt:Res Appl,2015,23(1):1-9.
[4] Marchioro A,Teuscher J,Friedrich D,et al.Unravelling the mechanism of photoinduced charge transfer processes in lead iodide perovskite solar cells[J].Nat Photonics,2014,8(3):250-255.
[5] Lee M M,Teuscher J,Miyasaka T,et al.Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites[J].Science,2012,338(6107):643-647.
[6] de Wolf S,Holovsky J,Moon S J,et al.Organometallic halide perovskites:sharp optical absorption edge and its relation to photovoltaic performance[J].J Phys Chem Lett,2014,5(6):1035-1039.
[7] Xing G,Mathews N,Sun S,et al.Long-range balanced electron-and hole-transport lengths in organic-inorganic CH3NH3PbI3[J].Science,2013,342(6156):344-347.
[8] Stranks S D,Eperon G E,Grancini G,et al.Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber[J].Science,2013,342(6156):341-344.
[9] Frost J M,Butler K T,Walsh A.Molecular ferroelectric contributions to anomalous hysteresis in hybrid perovskite solar cells[J].APL Mater,2014,2(8):081506.
[10] Wei J,Zhao Y,Li H,et al.Hysteresis analysis based on the ferroelectric effect in hybrid perovskite solar cells[J].J Phys Chem Lett,2014,5(21):3937-3945.
[11] Kutes Y,Ye L,Zhou Y,et al.Direct observation of ferroelectric domains in solution-processed CH3NH3PbI3 perovskite thin films[J].J Phys Chem Lett,2014,5(19):3335-3339.
[12] Gottesman R,Haltzi E,Gouda L,et al.Extremely slow photoconductivity response of CH3NH3PbI3 perovskites suggesting structural changes under working conditions[J].J Phys Chem Lett,2014,5(15):2662-2669.
[13] Sanchez R S,Gonzalez-Pedro V,Lee J W,et al.Slow dynamic processes in lead halide perovskite solar cells.Characteristic times and hysteresis[J].J Phys Chem Lett,2014,5(13):2357-2363.
[14] Snaith H J,Abate A,Ball J M,et al.Anomalous hysteresis in perovskite solar cells[J].J Phys Chem Lett,2014,5(9):1511-1515.
[15] Unger E L,Hoke E T,Bailie C D,et al.Hysteresis and transient behavior in current-voltage measurements of hybrid-perovskite absorber solar cells[J].Energy Environ Sci,2014,7(11):3690-3698.
[16] Chen H W,Sakai N,Ikegami M,et al.Emergence of hysteresis and transient ferroelectric response in organo-lead halide perovskite solar cells[J].J Phys Chem Lett,2015,6(1):164-169.
[17] Borriello I,Cantele G,Ninno D.Ab initio investigation of hybrid organic-inorganic perovskites based on tin halides[J].Phys Rev B Condens Matter Mater Phys,2008,77(23):235214.
[18] Stoumpos C C,Malliakas C D,Kanatzidis M G.Semiconducting tin and lead iodide perovskites with organic cations:phase transitions,high mobilities,and near-infrared photoluminescent properties[J].Inorg Chem,2013,52(15):9019-9038.
[19] Ogomi Y,Morita A,Tsukamoto S,et al.CH3NH3SnxPb(1-x)I3 perovskite solar cells covering up to 1 060 nm[J].J Phys Chem Lett,2014,5(6):1004-1011.
[20] Kitazawa N,Watanabe Y,Nakamura Y.Optical properties of CH3NH3PbX3(X=halogen)and their mixed-halide crystals[J].J Mater Sci,2002,37(17):3585-3587.
[21] Noh J H,Im S H,Heo J H,et al.Chemical management for colorful,efficient,and stable inorganic-organic hybrid nanostructured solar cells[J].Nano Lett,2013,13(4):1764-1769.
[22] Shi D,Adinolfi V,Comin R,et al.Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals[J].Science,2015,347(6221):519-522.
[23] Bach U,Lupo D,Comte P,et al.Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies[J].Nature,1998,395(6702):583-585.
[24] Xiao J,Shi J,Li D,et al.Perovskite thin-film solar cell:excitation in photovoltaic science[J].Sci China Chem,2015,58(2):221-238.
[25] Heo J H,Im S H,Noh J H,et al.Efficient inorganic-organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors[J].Nat Photonics,2013,7(6):486-491.
[26] Docampo P,Ball J M,Darwich M,et al.Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates[J].Nat Commun,2013,4:3761/1-3761/6.
[27] Malinkiewicz O,Yella A,Lee Y H,et al.Perovskite solar cells employing organic charge-transport layers[J].Nat Photonics,2014,8(2):128-132.
[28] Roldan-Carmona C,Malinkiewicz O,Soriano A,et al.Flexible high efficiency perovskite solar cells[J].Energy Environ Sci,2014,7(3):994-997.
[29] Christians J A,Fung R C M,Kamat P V.An inorganic hole conductor for organo-lead halide perovskite solar cells.improved hole conductivity with copper iodide[J].J Am Chem Soc,2014,136(2):758-764.
[30] Qin P,Tanaka S,Ito S,et al.Inorganic hole conductor-based lead halide perovskite solar cells with 12.4% conversion efficiency[J].Nat Commun,2014,5:3834.
[31] Wang K C,Shen P S,Li M H,et al.Low-temperature sputtered nickel oxide compact thin film as effective electron blocking layer for mesoscopic NiO/CH3NH3PbI3 perovskite heterojunction solar cells[J].ACS Appl Mater Interfaces,2014,6(15):11851-11858.
[32] Wu Z,Bai S,Xiang J,et al.Efficient planar heterojunction perovskite solar cells employing graphene oxide as hole conductor[J].Nanoscale,2014,6(18):10505-10510.
[33] Hu L,Wang W,Liu H,et al.PbS colloidal quantum dots as an effective hole transporter for planar heterojunction perovskite solar cells[J].J Mater Chem A,2015,3(2):515-518.
[34] Shi J J,Dong W,Xu Y Z,et al.Enhanced performance in perovskite organic lead iodide heterojunction solar cells with metal-insulator-semiconductor back contact[J].Chin Phys Lett,2013,30(12):128402.
[35] Ku Z,Rong Y,Xu M,et al.Full printable processed mesoscopic CH3NH3PbI3/TiO2 heterojunction solar cells with carbon counter electrode[J].Sci Rep,2013,3:3132.
[36] Mei A,Li X,Liu L,et al.A hole-conductor-free,fully printable mesoscopic perovskite solar cell with high stability[J].Science,2014,345(6194):295-298.
[37] Burschka J,Pellet N,Moon S J,et al.Sequential deposition as a route to high-performance perovskite-sensitized solar cells[J].Nature,2013,499(7458):316-319.
[38] Wang J T W,Ball J M,Barea E M,et al.Low-temperature processed electron collection layers of graphene/TiO2 nanocomposites in thin film perovskite solar cells[J].Nano Lett,2014,14(2):724-730.
[39] Yella A,Heiniger L P,Gao P,et al.Nanocrystalline rutile electron extraction layer enables low-temperature solution processed perovskite photovoltaics with 13.7% efficiency[J].Nano Lett,2014,14(5):2591-2596.
[40] Wu Y,Yang X,Chen H,et al.Highly compact TiO2 layer for efficient hole-blocking in perovskite solar cells[J].Appl Phys Express,2014,7(5):052301.
[41] Liu D,Kelly T L.Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques[J].Nat Photonics,2014,8(2):133-138.
[42] Jeng J Y,Chiang Y F,Lee M H,et al.CH3NH3PbI3 perovskite/fullerene planar-heterojunction hybrid solar cells[J].Adv Mater,2013,25(27):3727-3732.
[43] Seo J,Park S,Chan Kim Y,et al.Benefits of very thin PCBM and LiF layers for solution-processed p-i-n perovskite solar cells[J].Energy Environ Sci,2014,7(8):2642-2646.
[44] Wang Q,Shao Y,Dong Q,et al.Large fill-factor bilayer iodine perovskite solar cells fabricated by a low-temperature solution-process[J].Energy Environ Sci,2014,7(7):2359-2365.
[45] Nie W,Tsai H,Asadpour R,et al.High-efficiency solution-processed perovskite solar cells with millimeter-scale grains[J].Science,2015,347(6221):522-525.
[46] Chiang C H,Tseng Z L,Wu C G.Planar heterojunction perovskite/PC71BM solar cells with enhanced open-circuit voltage via a(2/1)-step spin-coating process[J].J Mater Chem A,2014,2(38):15897-15903.
[47] Zhu Z,Ma J,Wang Z,et al.Efficiency enhancement of perovskite solar cells through fast electron extraction:the role of graphene quantum dots[J].J Am Chem Soc,2014,136(10):3760-3763.
[48] Juarez-Perez E J,Wuβler M,Fabregat-Santiago F,et al.Role of the selective contacts in the performance of lead halide perovskite solar cells[J].J Phys Chem Lett,2014,5(4):680-685.
[49] Oh L S,Kim D H,Lee J A,et al.Zn2SnO4-based photoelectrodes for organolead halide perovskite solar cells[J].J Phys Chem C,2014,118(40):22991-22994.
[50] Gao P,Gratzel M,Nazeeruddin M K.Organohalide lead perovskites for photovoltaic applications[J].Energy Environ Sci,2014,7(8):2448-2463.
[51] Snaith H J.Perovskites:the emergence of a new era for low-cost,high-efficiency solar cells[J].J Phys Chem Lett,2013,4(21):3623-3630.
[52] Im J H,Lee C R,Lee J W,et al.6.5% efficient perovskite quantum-dot-sensitized solar cell[J].Nanoscale,2011,3(10):4088-4093.
[53] Kim H S,Lee C R,Im J H,et al.Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%[J].Sci Rep,2012,2:591.
[54] Bi D,Boschloo G,Schwarzmueller S,et al.Efficient and stable CH3NH3PbI3-sensitized ZnO nanorod array solid-state solar cells[J].Nanoscale,2013,5(23):11686-11691.
[55] Bi D,Moon S J,Haeggman L,et al.Using a two-step deposition technique to prepare perovskite(CH3NH3PbI3)for thin film solar cells based on ZrO2 and TiO2 mesostructures[J].RSC Adv,2013,3(41):18762-18766.
[56] Liu M,Johnston M B,Snaith H J.Efficient planar heterojunction perovskite solar cells by vapour deposition[J].Nature,2013,501(7467):395-398.
[57] Jeon N J,Noh J H,Kim Y C,et al.Solvent engineering for high-performance inorganic-organic hybrid perovskite solar cells[J].Nat Mater,2014,13(9):897-903.
[58] Ryu S,Noh J H,Jeon N J,et al.Voltage output of efficient perovskite solar cells with high open-circuit voltage and fill factor[J].Energy Environ Sci,2014,7(8):2614-2618.
[59] Xiao M,Huang F,Huang W,et al.A fast deposition-crystallization procedure for highly efficient lead iodide perovskite thin-film solar cells[J].Angew Chem Int Ed,2014,53(37):9898-9903.
[60] Wu Y,Islam A,Yang X,et al.Retarding the crystallization of PbI2 for highly reproducible planar-structured perovskite solar cells via sequential deposition[J].Energy Environ Sci,2014,7(9):2934-2938.
[61] Kim H B,Choi H,Jeong J,et al.Mixed solvents for the optimization of morphology in solution-processed,inverted-type perovskite/fullerene hybrid solar cells[J].Nanoscale,2014,6(12):6679-6683.
[62] Zhao Y,Zhu K.CH3NH3Cl-assisted one-step solution growth of CH3NH3PbI3:structure,charge-carrier dynamics,and photovoltaic properties of perovskite solar cells[J].J Phys Chem C,2014,118(18):9412-9418.
[63] Zuo C,Ding L.An 80.11% FF record achieved for perovskite solar cells by using the NH4Cl additive[J].Nanoscale,2014,6(17):9935-9938.
[64] Xiao Z,Bi C,Shao Y,et al.Efficient,high yield perovskite photovoltaic devices grown by interdiffusion of solution-processed precursor stacking layers[J].Energy Environ Sci,2014,7(8):2619-2623.
[65] Chen Q,Zhou H,Hong Z,et al.Planar heterojunction perovskite solar cells via vapor-assisted solution process[J].J Am Chem Soc,2014,136(2):622-625.
[66] Liu J,Wu Y,Qin C,et al.A dopant-free hole-transporting material for efficient and stable perovskite solar cells[J].Energy Environ Sci,2014,7(9):2963-2967.

备注/Memo

备注/Memo:
收稿日期:2015-03-17 录用日期:2014-06-10
基金项目:国家自然科学基金(21390391,U1205111); 中央高校基本科研业务费专项(20720140512)
*通信作者:denglinlong@xmu.edu.cn
引文格式:邓林龙,谢素原,黄荣彬,等.钙钛矿太阳能电池材料和器件的研究进展[J].厦门大学学报:自然科学版,2015,54(5):619-629.
Citation:Deng Linlong,Xie Suyuan,Huang Rongbin,et al.Research progress in perovskite solar cell materials and devices[J].Journal of Xiamen University:Natural Science,2015,54(5):619-629.(in Chinese)
更新日期/Last Update: 1900-01-01